Synthesis and redox properties of tetraethynyl tetrathiafulvalenes

被引：19

作者：

Solooki, D ^{[1
]}

Parker, TC ^{[1
]}

Khan, SI ^{[1
]}

Rubin, Y ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(98)00004-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and characterization of protected tetraethynyltetrathiafulvalenes (1a and 1b) is reported. The cation radical of 1a has a slightly more positive oxidation potential (E-ox0/1 = 0.63 V vs Ag/AgCl) than TTF. Stable CT solids can be prepared with iodine and TCNQF(4). These compounds are the first members of a series of highly unsaturated ?TF derivatives having in-plane pi-orbitals. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1327 / 1330

页数：4

共 35 条

[31] HALOGENATED TETRATHIAFULVALENES (TTFS) - PREPARATION, X-RAY STRUCTURE AND CYCLIC VOLTAMMETRY OF TETRACHLORO-2,3-DICHLORO-6,7-DIMETHYL-TTF AND TETRACHLORO-2,3-DIIODO-6,7-DIMETHYL-TTF [J].

WANG, CS ;

BECKER, JY ;

BERNSTEIN, J ;

ELLERN, A ;

KHODORKOVSKY, V .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (10) :1559-1562

[32] NEW DIRECT IODINATION OF TETRATHIAFULVALENE (TTF) - MONO-IODO-TTF AND DI-IODO-TTF AND THEIR X-RAY CRYSTAL-STRUCTURES [J].

WANG, CS ;

ELLERN, A ;

KHODORKOVSKY, V ;

BERNSTEIN, J ;

BECKER, JY .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (08) :983-984

[33]

Williams J. M., 1992, Organic Superconductors (Including Fullerenes): Synthesis, Structure, Properties, and Theory

[34] SYNTHESIS AND PROPERTIES OF 1,4-BUTENEDIYLIDENE-2,2'-BIS(1,3-DITHIOLE) [J].

YOSHIDA, Z ;

KAWASE, T ;

AWAJI, H ;

YONEDA, S .

TETRAHEDRON LETTERS, 1983, 24 (33) :3473-3476

[35] SYNTHESIS AND PROPERTIES OF ETHANEDIYLIDENE-2,2'-BIS(1,3-DITHIOLE) [J].

YOSHIDA, Z ;

KAWASE, T ;

AWAJI, H ;

SUGIMOTO, I ;

SUGIMOTO, T ;

YONEDA, S .

TETRAHEDRON LETTERS, 1983, 24 (33) :3469-3472

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