Nanostructured carbons in catalysis a Janus material-industrial applicability and fundamental insights

被引:90
作者
Bitter, J. H. [1 ]
机构
[1] Univ Utrecht, Debye Inst Nanomat Sci, Utrecht, Netherlands
关键词
NANOFIBER-SUPPORTED PLATINUM; OXIDATIVE DEHYDROGENATION; SELECTIVE HYDROGENATION; RUTHENIUM CATALYSTS; FUNCTIONAL-GROUPS; NANOTUBES; OXYGEN; DEPOSITION; SIZE; CINNAMALDEHYDE;
D O I
10.1039/c0jm00492h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nanostructured carbons especially carbon nanotubes and carbon nanofibers are Janus materials. As will be shown in this review one side of the Janus face is looking towards industrial applications. The availability of the materials is ever increasing and they can be produced at conditions which should make them profitable. Moreover their physical properties can be modified in such a way that application is viable. The other side of the face is looking towards fundamental understanding of heterogeneous catalysis. Insights in particle size and confinement effects emerged in the last few year using nanostructured carbon as a catalyst support. The carbons itself are effective oxidation and, after nitrogen incorporation, base catalysts. Examples will be discussed in this review.
引用
收藏
页码:7312 / 7321
页数:10
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共 98 条
[51]  
2-I
[52]   Mesoporous carbon nanotubes for use as support in catalysis and as nanosized reactors for one-dimensional inorganic material synthesis [J].
Nhut, JM ;
Pesant, L ;
Tessonnier, JP ;
Winé, G ;
Guille, J ;
Pham-Huu, C ;
Ledoux, MJ .
APPLIED CATALYSIS A-GENERAL, 2003, 254 (02) :345-363
[53]   Adsorption Mechanisms of Organic Chemicals on Carbon Nanotubes [J].
Pan, Bo ;
Xing, Baoshan .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (24) :9005-9013
[54]   Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles [J].
Pan, Xiulian ;
Fan, Zhongli ;
Chen, Wei ;
Ding, Yunjie ;
Luo, Hongyuan ;
Bao, Xinhe .
NATURE MATERIALS, 2007, 6 (07) :507-511
[55]   Reactions over catalysts confined in carbon nanotubes [J].
Pan, Xiulian ;
Bao, Xinhe .
CHEMICAL COMMUNICATIONS, 2008, (47) :6271-6281
[56]   Crucial Functionalizations of Carbon Nanotubes for Improved Drug Delivery: A Valuable Option? [J].
Pastorin, Giorgia .
PHARMACEUTICAL RESEARCH, 2009, 26 (04) :746-769
[57]   Catalytic activity of carbon nanotubes in the oxidative dehydrogenation of ethylbenzene [J].
Pereira, MFR ;
Figueiredo, JL ;
Orfao, JJM ;
Serp, P ;
Kalck, P ;
Kihn, Y .
CARBON, 2004, 42 (14) :2807-2813
[58]   Oxidative dehydrogenation of ethylbenzene on activated carbon catalysts. I. Influence of surface chemical groups [J].
Pereira, MFR ;
Orfao, JJM ;
Figueiredo, JL .
APPLIED CATALYSIS A-GENERAL, 1999, 184 (01) :153-160
[59]   Synthesis of CoFe2O4 nanowire in carbon nanotubes.: A new use of the confinement effect [J].
Pham-Huu, C ;
Keller, N ;
Estournès, C ;
Ehret, G ;
Ledoux, MJ .
CHEMICAL COMMUNICATIONS, 2002, (17) :1882-1883
[60]   Carbon nanomaterials with controlled macroscopic shapes as new catalytic materials [J].
Pham-Huu, Cuong ;
Ledoux, Marc-Jacques .
TOPICS IN CATALYSIS, 2006, 40 (1-4) :49-63