Asymmetric reductions of (trifluoroacetyl)biphenyl derivatives with bakers' yeast and with Geotrichum candidum acetone powder

被引：32

作者：

Fujisawa, T ^{[1
]}

Onogawa, Y ^{[1
]}

Sato, A ^{[1
]}

Mitsuya, T ^{[1
]}

Shimizu, M ^{[1
]}

机构：

[1] Mie Univ, Dept Chem Mat, Tsu, Mie 514, Japan

来源：

TETRAHEDRON | 1998年 / 54卷 / 17期

关键词：

D O I：

10.1016/S0040-4020(98)00144-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The bakers' yeast reduction of (trifluoroacetyl)biphenyl derivatives produces (R)-trifluoromethyl biphenylyl carbinols in high enantioselectivity, whereas the reduction of the same derivatives with Geotrichum candidum acetone powder gives the corresponding (S)-carbinols in excellent yields and enantioselectivity. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：4267 / 4276

页数：10

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