Silver(I)-catalyzed addition of zirconocenes to glycal epoxides.: A new synthesis of α-C-glycosides

被引：27

作者：

Wipf, P ^{[1
]}

Pierce, JG

Zhuang, N

机构：

[1] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

[2] Univ Pittsburgh, Ctr Chem Methodol & Library Dev, Pittsburgh, PA 15260 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 03期

关键词：

D O I：

10.1021/ol0475414

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrozirconation of terminal alkynes, followed by AgClO4-catalyzed in situ addition of the resultant alkenylzirconocenes to 1,2-anhydrosugars (glycal epoxides) leads to alpha-C-glycosides in moderate to high yields.

引用

页码：483 / 485

页数：3

共 43 条

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