Orbital and spin chains in ZnV2O4 -: art. no. 156407

被引:253
作者
Lee, SH [1 ]
Louca, D
Ueda, H
Park, S
Sato, TJ
Isobe, M
Ueda, Y
Rosenkranz, S
Zschack, P
Iñiguez, J
Qiu, Y
Osborn, R
机构
[1] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA
[2] Univ Virginia, Dept Phys, Charlottesville, VA 22904 USA
[3] Univ Tokyo, Inst Solid State Phys, Chiba 2778581, Japan
[4] Korea Atom Energy Res Inst, HANARO Ctr, Taejon, South Korea
[5] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
[6] Univ Illinois, Frederick Seitz Mat Res Lab, Urbana, IL 61801 USA
基金
美国国家科学基金会;
关键词
D O I
10.1103/PhysRevLett.93.156407
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Our powder inelastic neutron scattering data indicate that ZnV2O4 is a system of spin chains that are three-dimensionally tangled in the cubic phase above 50 K due to randomly occupied t(2g) orbitals of V3+ (3d(2)) ions. Below 50 K in the tetragonal phase, the chains become straight due to antiferro-orbital ordering. This is evidenced by the characteristic wave vector dependence of the magnetic structure factor that changes from symmetric to asymmetric at the cubic-to-tetragonal transition.
引用
收藏
页码:156407 / 1
页数:4
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