Fabrication of NOx gas sensors using In2O3-ZnO composite films

被引:112
作者
Lin, Chia-Yu [1 ]
Fang, Yueh-Yuan [2 ]
Lin, Chii-Wann [2 ,3 ]
Tunney, James J. [4 ]
Ho, Kuo-Chuan [1 ,5 ]
机构
[1] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan
[2] Natl Taiwan Univ, Inst Biomed Engn, Taipei 10617, Taiwan
[3] Natl Taiwan Univ, Inst Elect Engn, Taipei 10617, Taiwan
[4] Natl Res Council Canada, Inst Chem Proc & Environm Technol, Ottawa, ON K1A 0R6, Canada
[5] Natl Taiwan Univ, Inst Polymer Sci & Engn, Taipei 10617, Taiwan
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2010年 / 146卷 / 01期
关键词
Gas sensor; Indium oxide; In2O3-ZnO; Nitric oxide; Zinc oxide; SENSING CHARACTERISTICS; THIN-FILM; OXIDES; ZNO; NANORODS;
D O I
10.1016/j.snb.2010.02.040
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In2O3-ZnO composite films were fabricated and their NOx sensing characteristics were investigated in this study. The content of ZnO in In2O3-ZnO film was controlled by adjusting the Zn2+/In3+ molar ratio (r) during the film preparation. With suitable amount of ZnO incorporated into the ln(2)O(3) films, the responses of the composite films to NOx at operation temperatures below 200 degrees C were greatly improved. However, as the ZnO content was further increased, the grain of the composite film started to merge into big ones, thus decreasing the surface area and resulting in lower sensor responses. The detection limit (S/N = 3) of In2O3-ZnO composite film (r = 0.67) reached 12 ppb at 150 degrees C. Both pure In2O3 (r = 0) and In2O3-ZnO composite films (r = 0.67) showed no response to CO gas. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:28 / 34
页数:7
相关论文
共 28 条
[1]   Bi2O3 as a selective sensing material for NO detection [J].
Cabot, A ;
Marsal, A ;
Arbiol, J ;
Morante, JR .
SENSORS AND ACTUATORS B-CHEMICAL, 2004, 99 (01) :74-89
[2]  
CHIMBEU CM, 2009, MATER CHEM PHYS, V114, P933
[3]   NO2 sensing characteristics of ZnO nanorods prepared by hydrothermal method [J].
Cho, Pyeong-Seok ;
Kim, Ki-Won ;
Lee, Jong-Heun .
JOURNAL OF ELECTROCERAMICS, 2006, 17 (2-4) :975-978
[4]   Increased exhaled nitric oxide in chronic bronchitis - Comparison with asthma and COPD [J].
Delen, FM ;
Sippel, JM ;
Osborne, ML ;
Law, S ;
Thukkani, N ;
Holden, WE .
CHEST, 2000, 117 (03) :695-701
[5]   Porous indium oxide nanotubes:: Layer-by-layer assembly on carbon-nanotube templates and application for room-temperature NH3 gas sensors [J].
Du, Ning ;
Zhang, Hui ;
Chen, Bindi ;
Ma, Xiangyang ;
Liu, Zhihong ;
Wu, Jianbo ;
Yang, Deren .
ADVANCED MATERIALS, 2007, 19 (12) :1641-+
[6]   Chemical synthesis of In2O3 nanocrystals and their application in highly performing ozone-sensing devices [J].
Epifani, Mauro ;
Comini, Elisabetta ;
Arbiol, Jordi ;
Diaz, Raul ;
Sergent, Nicolas ;
Pagnier, Thierry ;
Siciliano, Pietro ;
Faglia, Guido ;
Morante, Joan R. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 130 (01) :483-487
[7]   NO2-gas-sensing properties of mixed In2O3-SnO2 thin films [J].
Forleo, A ;
Francioso, L ;
Epifani, M ;
Capone, S ;
Taurino, AM ;
Siciliano, P .
THIN SOLID FILMS, 2005, 490 (01) :68-73
[8]   Nanostructured In2O3-SnO2 sol-gel thin film as material for NO2 detection [J].
Francioso, L ;
Forleo, A ;
Capone, S ;
Epifani, M ;
Taurino, AM ;
Siciliano, P .
SENSORS AND ACTUATORS B-CHEMICAL, 2006, 114 (02) :646-655
[9]   Grain size control in nanocrystalline In2O3 semiconductor gas sensors [J].
Gurlo, A ;
Ivanovskaya, M ;
Barsan, N ;
Schweizer-Berberich, M ;
Weimar, U ;
Gopel, W ;
Dieguez, A .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 44 (1-3) :327-333
[10]   Differential mechanisms underlying the modulation of delayed-rectifier K+ channel in mouse neocortical neurons by nitric oxide [J].
Han, NLR ;
Ye, JS ;
Yu, ACH ;
Sheu, FS .
JOURNAL OF NEUROPHYSIOLOGY, 2006, 95 (04) :2167-2178