Flexible metal-organic supramolecular isomers for gas separation

被引:151
作者
Kishan, Motkuri Radha [1 ]
Tian, Jian [2 ]
Thallapally, Praveen K. [1 ]
Fernandez, Carlos A. [1 ]
Dalgarno, Scott J. [3 ]
Warren, John E. [4 ]
McGrail, B. Peter [1 ]
Atwood, Jerry L. [2 ]
机构
[1] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA
[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
[3] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland
[4] Daresbury Sci & Innovat Campus, Warrington WA4 4AD, Cheshire, England
关键词
CARBON-DIOXIDE; COORDINATION POLYMER; HYDROGEN STORAGE; METHANE STORAGE; HIGH-CAPACITY; FRAMEWORKS; ADSORPTION; SITES; CO2; MOLECULES;
D O I
10.1039/b913910a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three interpenetrated metal-organic supramolecular isomers were synthesised using a flexible tetrahedral organic linker and Zn(2) clusters that sorb CO(2) preferably over N(2), H(2) and methane at room temperature.
引用
收藏
页码:538 / 540
页数:3
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