Hydrothermal synthesis of two-dimensional organic-inorganic hybrid materials of the nickel-molybdate family:: the structures of [{Ni(3,3′-bpy)2}2Mo4O14] and [Ni(3,3′-Hbpy)Mo4O13(OH)]

被引：60

作者：

LaDuca, RL ^{[1
]}

Desciak, M

Laskoski, M

Rarig, RS

Zubieta, J

机构：

[1] Kings Coll London, Dept Chem & Phys, Wilkes Barre, PA 18711 USA

[2] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b001419m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal chemistry of the Ni(II)/molybdate/3,3'-bipyridine system exhibits pronounced pH dependence, such that under basic conditions a 2-D material with embedded clusters [{Ni(3,3'-bpy)(2)}(2)Mo4O14] 1 is observed, while under acidic conditions the 2-D bimetallic oxide network of [Ni(3,3'-Hbpy)Mo4O13(OH)] 2 is isolated.

引用

页码：2255 / 2257

页数：3

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