Printed all-polymer electrochemical transistors on patterned ion conducting membranes

被引:29
作者
Kaihovirta, Nikolai [1 ,2 ,4 ]
Makela, Tapio [1 ,2 ]
He, Xuehan [1 ,3 ]
Wikman, Carl-Johan [1 ,3 ]
Wilen, Carl-Eric [1 ,3 ]
Osterbacka, Ronald [1 ,2 ]
机构
[1] Abo Akad Univ, Ctr Funct Mat, FI-20500 Turku, Finland
[2] Abo Akad Univ, Dept Nat Sci, FI-20500 Turku, Finland
[3] Abo Akad Univ, Dept Chem Engn, FI-20500 Turku, Finland
[4] Turku Univ, Grad Sch Mat Res, FI-20500 Turku, Finland
基金
芬兰科学院;
关键词
Electrochemical transistor; Organic transistor; All-polymer; PEDOT/PSS; Roll-to-roll; WORM; THIN-FILM TRANSISTORS; OVER-OXIDATION; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); POLYTHIOPHENES; ELECTRONICS; CIRCUITS; MEMORY; LOGIC; CELLS;
D O I
10.1016/j.orgel.2010.04.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report a simple and roll-to-roll suitable method of manufacturing low-voltage, all-polymer electrochemical transistors (ECTs). The ECTs are built on self-supported and patterned ion conducting membranes that are tailor-made by the electron beam irradiation induced grafting technique. The redox-active poly(3,4-ethylene dioxythiophene)/poly(styrene sulfonate) (PEDOT/PSS) is then printed by flexography onto the membrane in one fabrication step. The ECTs are "normally-on" devices that operate below 2 V. We also utilize overoxidation of PEDOT in order to demonstrate write-once read many times (WORM) memory functionality in the ECT. (c) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1207 / 1211
页数:5
相关论文
共 27 条
[1]   Printable all-organic electrochromic active-matrix displays [J].
Andersson, Peter ;
Forchheimer, Robert ;
Tehrani, Payman ;
Berggren, Magnus .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (16) :3074-3082
[2]   Anodic overoxidation of polythiophenes in wet acetonitrile electrolytes [J].
Barsch, U ;
Beck, F .
ELECTROCHIMICA ACTA, 1996, 41 (11-12) :1761-1771
[3]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[4]  
2-9
[5]  
Hamedi M, 2007, NAT MATER, V6, P357, DOI [10.1038/nmat1884, 10.1038/nma11884]
[6]   Electronic control of Ca2+ signalling in neuronal cells using an organic electronic ion pump [J].
Isaksson, Joakim ;
Kjaell, Peter ;
Nilsson, David ;
Robinson, Nathaniel D. ;
Berggren, Magnus ;
Richter-Dahlfors, Agneta .
NATURE MATERIALS, 2007, 6 (09) :673-679
[7]   Self-Supported Ion-Conductive Membrane-Based Transistors [J].
Kaihovirta, Nikolai J. ;
Wikman, Carl-Johan ;
Makela, Tapio ;
Wilen, Carl-Eric ;
Osterbacka, Ronald .
ADVANCED MATERIALS, 2009, 21 (24) :2520-+
[8]  
Kipphan H., 2001, HDB PRINT MEDIA
[9]   Electrochemical oxidation of poly(3,4-ethylenedioxythiophene) - "in situ" conductivity and spectroscopic investigations [J].
Lapkowski, M ;
Pron, A .
SYNTHETIC METALS, 2000, 110 (01) :79-83
[10]   Electrochemical characterization of PVDF-based proton conducting membranes for fuel cells [J].
Lehtinen, T ;
Sundholm, G ;
Holmberg, S ;
Sundholm, F ;
Bjornbom, P ;
Bursell, M .
ELECTROCHIMICA ACTA, 1998, 43 (12-13) :1881-1890