Printed all-polymer electrochemical transistors on patterned ion conducting membranes

被引:29
作者
Kaihovirta, Nikolai [1 ,2 ,4 ]
Makela, Tapio [1 ,2 ]
He, Xuehan [1 ,3 ]
Wikman, Carl-Johan [1 ,3 ]
Wilen, Carl-Eric [1 ,3 ]
Osterbacka, Ronald [1 ,2 ]
机构
[1] Abo Akad Univ, Ctr Funct Mat, FI-20500 Turku, Finland
[2] Abo Akad Univ, Dept Nat Sci, FI-20500 Turku, Finland
[3] Abo Akad Univ, Dept Chem Engn, FI-20500 Turku, Finland
[4] Turku Univ, Grad Sch Mat Res, FI-20500 Turku, Finland
基金
芬兰科学院;
关键词
Electrochemical transistor; Organic transistor; All-polymer; PEDOT/PSS; Roll-to-roll; WORM; THIN-FILM TRANSISTORS; OVER-OXIDATION; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); POLYTHIOPHENES; ELECTRONICS; CIRCUITS; MEMORY; LOGIC; CELLS;
D O I
10.1016/j.orgel.2010.04.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report a simple and roll-to-roll suitable method of manufacturing low-voltage, all-polymer electrochemical transistors (ECTs). The ECTs are built on self-supported and patterned ion conducting membranes that are tailor-made by the electron beam irradiation induced grafting technique. The redox-active poly(3,4-ethylene dioxythiophene)/poly(styrene sulfonate) (PEDOT/PSS) is then printed by flexography onto the membrane in one fabrication step. The ECTs are "normally-on" devices that operate below 2 V. We also utilize overoxidation of PEDOT in order to demonstrate write-once read many times (WORM) memory functionality in the ECT. (c) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1207 / 1211
页数:5
相关论文
共 27 条
[11]   The morphology control of pentacene for write-once-read-many-times memory devices [J].
Lin, Jian ;
Ma, Dongge .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (02)
[12]   Chemical and biological sensors based on organic thin-film transistors [J].
Mabeck, JT ;
Malliaras, GG .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2006, 384 (02) :343-353
[13]   Inkjet printed electrochemical organic electronics [J].
Mannerbro, Richard ;
Ranlof, Martin ;
Robinson, Nathaniel ;
Forchheimer, Robert .
SYNTHETIC METALS, 2008, 158 (13) :556-560
[14]   A polymer/semiconductor write-once read-many-times memory [J].
Möller, S ;
Perlov, C ;
Jackson, W ;
Taussig, C ;
Forrest, SR .
NATURE, 2003, 426 (6963) :166-169
[15]   Conductivity, work function, and environmental stability of PEDOT:PSS thin films treated with sorbitol [J].
Nardes, A. M. ;
Kemerink, M. ;
de Kok, M. M. ;
Vinken, E. ;
Maturova, K. ;
Janssen, R. A. J. .
ORGANIC ELECTRONICS, 2008, 9 (05) :727-734
[16]   Electrochemical logic circuits [J].
Nilsson, D ;
Robinson, N ;
Berggren, M ;
Forchheimer, R .
ADVANCED MATERIALS, 2005, 17 (03) :353-+
[17]  
Nilsson D, 2002, ADV MATER, V14, P51, DOI 10.1002/1521-4095(20020104)14:1<51::AID-ADMA51>3.0.CO
[18]  
2-#
[19]   POTENTIAL DEPENDENCE OF THE CONDUCTIVITY OF HIGHLY OXIDIZED POLYTHIOPHENES, POLYPYRROLES, AND POLYANILINE - FINITE WINDOWS OF HIGH CONDUCTIVITY [J].
OFER, D ;
CROOKS, RM ;
WRIGHTON, MS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (22) :7869-7879
[20]   Exploiting ionic coupling in electronic devices: Electrolyte-gated organic field-effect transistors [J].
Panzer, Matthew J. ;
Frisbie, C. Daniel .
ADVANCED MATERIALS, 2008, 20 (16) :3177-3180