Band alignment between (100)Si and complex rare earth/transition metal oxides

被引:131
作者
Afanas'ev, VV
Stesmans, A
Zhao, C
Caymax, M
Heeg, T
Schubert, J
Jia, Y
Schlom, DG
Lucovsky, G
机构
[1] Univ Leuven, Dept Phys, B-3001 Louvain, Belgium
[2] IMEC, B-3001 Louvain, Belgium
[3] Forschungszentrum Julich, Inst Schichten & Grenzflachen, D-52425 Julich, Germany
[4] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[5] N Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA
关键词
D O I
10.1063/1.1829781
中图分类号
O59 [应用物理学];
学科分类号
摘要
The electron energy band alignment between (100)Si and several complex transition/rare earth (RE) metal oxides (LaScO3, GdScO3, DyScO3, and LaAlO3, all in amorphous form) is determined using a combination of internal photoemission and photoconductivity measurements. The band gap width is nearly the same in all the oxides (5.6-5.7 eV) yielding the conduction and valence band offsets at the Si/oxide interface of 2.0+/-0.1 and 2.5+/-0.1 eV, respectively. However, band-tail states are observed and these are associated with Jahn-Teller relaxation of transition metal and RE cations which splits their d* states. (C) 2004 American Institute of Physics.
引用
收藏
页码:5917 / 5919
页数:3
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