Intense near-infrared optical absorbing emerald green [60]fullerenes

被引:54
作者
Canteenwala, T [1 ]
Padmawar, PA [1 ]
Chiang, LY [1 ]
机构
[1] Univ Massachusetts, Inst Nanosci & Engn Technol, Dept Chem, Lowell, MA 01854 USA
关键词
D O I
10.1021/ja044409q
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis of emerald green fullerenes (EF) C60[C(CH3)(CO2Et)2]6 and C60[C(CH3)(CO2-t-Bu)2]6 was performed by using hexaanionic C60 intermediate (C60-6) as a reagent in one-pot reaction for attaching six alkyl ester addends on one C60 cage. These EF compounds exhibit intense optical absorption over 600-940 nm, the longest optical absorption of the C60 cage among many [60]fullerene derivatives synthesized. Copyright © 2005 American Chemical Society.
引用
收藏
页码:26 / 27
页数:2
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