Metallomesogens by ligand design

被引:113
作者
Date, RW [1 ]
Iglesias, EF [1 ]
Rowe, KE [1 ]
Elliott, JM [1 ]
Bruce, DW [1 ]
机构
[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England
关键词
D O I
10.1039/b212610a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this Perspective, some of the basic principles of ligand design will be described as they apply to the synthesis of metal complexes with liquid crystal properties. Liquid crystal properties of metal complexes are a delicate function of both ligand and metal and examples will be chosen to illustrate this statement. In particular, the effect of the metal complex moiety on the mesomorphism of a series of imine and diimine liquid crystals is described.
引用
收藏
页码:1914 / 1931
页数:18
相关论文
共 112 条
[11]   Copper-containing dendromesogens:: the influence of the metal on the mesomorphism [J].
Barberá, J ;
Marcos, M ;
Omenat, A ;
Serrano, JL ;
Martínez, JI ;
Alonso, PJ .
LIQUID CRYSTALS, 2000, 27 (02) :255-262
[12]  
Barberá J, 1999, CHEM-EUR J, V5, P1834, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1834::AID-CHEM1834>3.0.CO
[13]  
2-A
[14]   Pyrazolate ''golden'' rings: Trinuclear complexes that form columnar mesophases at room temperature [J].
Barbera, J ;
Elduque, A ;
Gimenez, R ;
Oro, LA ;
Serrano, JL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (23-24) :2832-2835
[15]   GREATLY ENHANCED ELECTRONIC POLARIZABILITIES IN METAL-CONTAINING LIQUID-CRYSTALS [J].
BERTRAM, C ;
BRUCE, DW ;
DUNMUR, DA ;
HUNT, SE ;
MAITLIS, PM ;
MCCANN, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (02) :69-70
[16]   Lanthanide-containing liquid crystals and surfactants [J].
Binnemans, K ;
Görller-Walrand, C .
CHEMICAL REVIEWS, 2002, 102 (06) :2303-2345
[17]   Towards magnetic liquid crystals [J].
Binnemans, K ;
Bruce, DW ;
Collinson, SR ;
Van Deun, R ;
Galymetdinov, YG ;
Martin, F .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1999, 357 (1762) :3063-3077
[18]   LIQUID-CRYSTALLINE COMPLEXES OF OCTAHEDRAL MANGANESE(I) [J].
BRUCE, DW ;
LIU, XH .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (06) :729-730
[19]   HIGH COORDINATION-NUMBER CALAMITIC METALLOMESOGENS [J].
BRUCE, DW .
ADVANCED MATERIALS, 1994, 6 (09) :699-701
[20]   SYNTHESIS AND MESOMORPHISM OF STILBAZOLE COMPLEXES OF RHODIUM(I) AND IRIDIUM(I) [J].
BRUCE, DW ;
DUNMUR, DA ;
ESTERUELAS, MA ;
HUNT, SE ;
LELAGADEC, R ;
MAITLIS, PM ;
MARSDEN, JR ;
SOLA, E ;
STACEY, JM .
JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (02) :251-254