Gold-catalyzed direct amination of allylic alcohols

被引：84

作者：

Guo, Shenghai ^{[1
]}

Song, Feijie ^{[1
]}

Liu, Yuanhong ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

SYNLETT | 2007年 / 06期

关键词：

gold catalysis; allylic alcohols; amination; nucleophilic substitution; synthetic methods;

D O I：

10.1055/s-2007-973865

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and direct synthesis of allylic amines from allylic alcohols was developed by utilization of gold complexes as catalysts under mild reaction conditions. AuCl3 proved to be a better catalyst than a cationic gold(I) complex of AuCl(PPh3)/AgOTf.

引用

页码：964 / 968

页数：5

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