Carbon-Fluorine Bond Formation for the Synthesis of Aryl Fluorides

被引：186

作者：

Furuya, Takeru ^{[1
]}

Klein, Johannes E. M. N. ^{[1
]}

Ritter, Tobias ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

SYNTHESIS-STUTTGART | 2010年 / 11期

关键词：

carbon-fluorine bond formation; transition metals; palladium; silver; catalysis; FORMING REDUCTIVE ELIMINATION; ENANTIOSELECTIVE VINYLOGOUS MANNICH; TRIMETHOXYSILYL ENOL ETHERS; SAKURAI-HOSOMI ALLYLATION; ASYMMETRIC ALDOL REACTION; CROSS-COUPLING REACTIONS; HIGHLY-ACTIVE CATALYST; ELECTROPHILIC FLUORINATION; C-O; OXIDATIVE ADDITION;

D O I：

10.1055/s-0029-1218742

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A selection of carbon-fluorine bond-forming reactions is presented with particular focus on transition-metal-mediated fluorination. A brief summary of conventional fluorination reactions is followed by a discussion of fluorination reactions mediated by palladium and silver. Investigations into the mechanism as well as the conceptual difficulty associated with transition-metal-mediated carbon-fluorine bond formation are presented.

引用

页码：1804 / 1821

页数：18

共 182 条

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