Dual Redox Responsive Assemblies Formed from Diselenide Block Copolymers

被引:737
作者
Ma, Ning [1 ]
Li, Ying [1 ]
Xu, Huaping [1 ]
Wang, Zhiqiang [1 ]
Zhang, Xi [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
GLUTATHIONE-PEROXIDASE; SUPRAMOLECULAR ASSEMBLIES; SELENIUM CHEMISTRY; DRUG-DELIVERY; VESICLES; MICELLES; POLYMERS; LIGHT;
D O I
10.1021/ja908124g
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A block copolymer with diselenide bonds in the polymer backbone was reported. This block copolymer was capable of forming micellar aggregates that were responsive to redox stimuli. Compared with other redox responsive aggregates, this type of diselenide-containing block copolymer aggregates Could be responsive to both oxidants and reductants even in a solution with a very low concentration under mild conditions.
引用
收藏
页码:442 / +
页数:4
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