Alcoholysis route to monodisperse CoO nanotetrapods with tunable size

被引:19
作者
Zhang, Yuliang
Zhong, Xinhua [1 ]
Zhu, Jian
Song, Xin
机构
[1] E China Univ Sci & Technol, Dept Chem, Adv Mat Lab, Shanghai 200237, Peoples R China
[2] Tongji Univ, Sch Life Sci & Technol, Shanghai 200092, Peoples R China
关键词
D O I
10.1088/0957-4484/18/19/195605
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Monodisperse tetrapod-shaped CoO nanocrystals were prepared via the alcoholysis of cobalt (III) oleate in dodecanol at high temperature. The coordinating solvent dodecanol also acts as a reducing and morphology controller reagent. The size of the obtained CoO nanotetrapods can be well tuned by variation of the amount of dodecanol used. The chemical composition, structure and morphology of the obtained nanocrystals were characterized by using energy-dispersive x-ray analysis, powder x-ray diffraction, and transmission electron microscopy.
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页数:5
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共 61 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   Synthesis, characterization, and self-assembly of pencil-shaped CoO nanorods [J].
An, Kwangjin ;
Lee, Nohyun ;
Park, Jongnam ;
Kim, Sung Chul ;
Hwang, Yosun ;
Park, Je-Geun ;
Kim, Jae-Young ;
Park, Jae-Hoon ;
Han, Myung Joon ;
Yu, Jaejun ;
Hyeon, Taeghwan .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9753-9760
[3]   Chemistry and properties of nanocrystals of different shapes [J].
Burda, C ;
Chen, XB ;
Narayanan, R ;
El-Sayed, MA .
CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102
[4]   Hierarchically structured cobalt oxide (Co3O4):: The morphology control and its potential in sensors [J].
Cao, An-Min ;
Hu, Jin-Song ;
Liang, Han-Pu ;
Song, Wei-Guo ;
Wan, Li-Jun ;
He, Xiu-Li ;
Gao, Xiao-Guang ;
Xia, Shan-Hong .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (32) :15858-15863
[5]   Multiple wurtzite twinning in CdTe nanocrystals induced by methylphosphonic acid [J].
Carbone, L ;
Kudera, S ;
Carlino, E ;
Parak, WJ ;
Giannini, C ;
Cingolani, R ;
Manna, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) :748-755
[6]   Polyol synthesis of platinum nanostructures: Control of morphology through the manipulation of reduction kinetics [J].
Chen, JY ;
Herricks, T ;
Xia, YN .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (17) :2589-2592
[7]   Monopod, bipod, tripod, and tetrapod gold nanocrystals [J].
Chen, SH ;
Wang, ZL ;
Ballato, J ;
Foulger, SH ;
Carroll, DL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (52) :16186-16187
[8]   Colloidal synthesis and characterization of tetrapod-shaped magnetic nanocrystals [J].
Cozzoli, P. Davide ;
Snoeck, Etienne ;
Garcia, Miguel Angel ;
Giannini, Cinzia ;
Guagliardi, Antonietta ;
Cervellino, Antonio ;
Gozzo, Fabia ;
Hernando, Antonio ;
Achterhold, Klaus ;
Ciobanu, Nelica ;
Parak, Fritz G. ;
Cingolani, Roberto ;
Manna, Liberato .
NANO LETTERS, 2006, 6 (09) :1966-1972
[9]   Shape and phase control of colloidal ZnSe nanocrystals [J].
Cozzoli, PD ;
Manna, L ;
Curri, ML ;
Kudera, S ;
Giannini, C ;
Striccoli, M ;
Agostiano, A .
CHEMISTRY OF MATERIALS, 2005, 17 (06) :1296-1306
[10]   Electrical transport through a single nanoscale semiconductor branch point [J].
Cui, Y ;
Banin, U ;
Björk, MT ;
Alivisatos, AP .
NANO LETTERS, 2005, 5 (07) :1519-1523