Mechanism of the partial oxidation of methane to synthesis gas over Pd

被引：40

作者：

van Looij, F ^{[1
]}

Stobbe, ER ^{[1
]}

Geus, JW ^{[1
]}

机构：

[1] Debije Inst, Dept Inorgan Chem, NL-3584 CA Utrecht, Netherlands

来源：

CATALYSIS LETTERS | 1998年 / 50卷 / 1-2期

关键词：

partial oxidation; synthesis gas; methane; palladium; carbon filaments;

D O I：

10.1023/A:1019090213003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The partial oxidation of methane to synthesis gas has been studied in an isothermal continuous flow reactor operated with the phases in plug flow, using a silica-supported palladium catalyst. The reaction mechanism involves the sequential combustion and reforming of methane. The catalyst bed is not uniform in terms of the composition of the palladium phase. The implications for investigations using a pulse apparatus are discussed. Finally, large palladium crystallites readily grow carbon filaments.

引用

页码：59 / 67

页数：9

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