[Bis(trimethylsilyl)amido](η5-pentamethylcyclopentadienyl)iron(II):: A diamagnetic 14-electron complex with a "pogo-stick" structure

被引：42

作者：

Siemeling, U ^{[1
]}

Vorfeld, U ^{[1
]}

Neumann, B ^{[1
]}

Stammler, HG ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 03期

关键词：

D O I：

10.1021/om9707432

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The half-sandwich complex Cp*FeN(SiMe3)(2) was synthesized by the reaction, of iron(II) chloride in THF with 1 equiv of KN(SiMe3)(2) and subsequent addition of Cp*Li and was structurally characterized by X-ray diffraction; its "pogo-stick" structure is unprecedented in the chemistry of open-shell organometallics.

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页码：483 / 484

页数：2

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