Synthesis and catalytic properties of new water-soluble ruthenium(II)-N-heterocyclic carbene complexes

被引：99

作者：

Csabai, P

Joó, F

机构：

[1] Univ Debrecen, Inst Phys Chem, H-4010 Debrecen, Hungary

[2] Hungarian Acad Sci, Res Grp Homogeneous Catalysis, H-4010 Debrecen, Hungary

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 23期

关键词：

D O I：

10.1021/om049511a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new water-soluble complexes [RuXY(1-butyl-3-methylimidazol-2-ylidene)(p-cymene)](n+) (X = Cl-, H2O; Y = Cl-, H2O, 1,3,5-triaza-7-phosphaadamantane (pta); n = 0-2) catalyze the hydrogenation of various olefins, aldehydes, and ketones and the redox isomerization of allyl alcohol in aqueous solution under mild conditions and are suitable for the modification of lipid membranes by catalytic hydrogenation.

引用

收藏

页码：5640 / 5643

页数：4

相关论文

共 66 条

[1] Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM [J].

Ackermann, L ;

Fürstner, A ;

Weskamp, T ;

Kohl, FJ ;

Herrmann, WA .

TETRAHEDRON LETTERS, 1999, 40 (26) :4787-4790

[2] Chelated iridium(III) bis-carbene complexes as air-stable catalysts for transfer hydrogenation [J].

Albrecht, M ;

Miecznikowski, JR ;

Samuel, A ;

Faller, JW ;

Crabtree, RH .

ORGANOMETALLICS, 2002, 21 (17) :3596-3604

[3] Synthesis and characterisation of some water soluble ruthenium(II)-arene complexes and an investigation of their antibiotic and antiviral properties [J].

Allardyce, CS ;

Dyson, PJ ;

Ellis, DJ ;

Salter, PA ;

Scopelliti, R .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 668 (1-2) :35-42

[4] Formation and stability of N-heterocyclic carbenes in water:: The carbon acid pKa of imidazollum cations in aqueous solution [J].

Amyes, TL ;

Diver, ST ;

Richard, JP ;

Rivas, FM ;

Toth, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (13) :4366-4374

[5] ARENE RUTHENIUM(II) COMPLEXES FORMED BY DEHYDROGENATION OF CYCLOHEXADIENES WITH RUTHENIUM(III) TRICHLORIDE [J].

BENNETT, MA ;

SMITH, AK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (02) :233-241

[6]

Böhm VPW, 2000, ANGEW CHEM INT EDIT, V39, P1602, DOI 10.1002/(SICI)1521-3773(20000502)39:9<1602::AID-ANIE1602>3.0.CO

[7]

2-N

[8] Activation and deactivation of a carbene containing non-classical ruthenium hydride complex in catalytic processes involving C-H bond cleavage [J].

Buskens, P ;

Giunta, D ;

Leitner, W .

INORGANICA CHIMICA ACTA, 2004, 357 (06) :1969-1974

[9] Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV):: a highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media [J].

Cadierno, V ;

García-Garrido, SE ;

Gimeno, J .

CHEMICAL COMMUNICATIONS, 2004, (02) :232-233

[10] η6-mesityl,η1-imidazolinylidene-carbene-ruthenium(II) complexes:: Catalytic activity of their allenylidene derivatives in alkene metathesis and cycloisomerisation reactions [J].

Çetinkaya, B ;

Demir, S ;

Özdemir, I ;

Toupet, L ;

Sémeril, D ;

Bruneau, C ;

Dixneuf, PH .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (10) :2323-2330

← 1 2 3 4 5 6 7 →