Synthesis and catalytic properties of new water-soluble ruthenium(II)-N-heterocyclic carbene complexes

被引：99

作者：

Csabai, P

Joó, F

机构：

[1] Univ Debrecen, Inst Phys Chem, H-4010 Debrecen, Hungary

[2] Hungarian Acad Sci, Res Grp Homogeneous Catalysis, H-4010 Debrecen, Hungary

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 23期

关键词：

D O I：

10.1021/om049511a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new water-soluble complexes [RuXY(1-butyl-3-methylimidazol-2-ylidene)(p-cymene)](n+) (X = Cl-, H2O; Y = Cl-, H2O, 1,3,5-triaza-7-phosphaadamantane (pta); n = 0-2) catalyze the hydrogenation of various olefins, aldehydes, and ketones and the redox isomerization of allyl alcohol in aqueous solution under mild conditions and are suitable for the modification of lipid membranes by catalytic hydrogenation.

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页码：5640 / 5643

页数：4

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