Structural and Catalytic Performance of a Polyoxometalate-Based Metal-Organic Framework Having a Lanthanide Nanocage as a Secondary Building Block

被引：95

作者：

Dang, Dongbin ^{[1
,2
]}

Bai, Yan ^{[2
]}

He, Cheng ^{[1
]}

Wang, Jian ^{[1
]}

Duan, Chunying ^{[1
]}

Niu, Jingyang ^{[2
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

[2] Henan Univ, Inst Mol & Crystal Engn, Sch Chem & Chem Engn, Kaifeng 475004, Peoples R China

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 04期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

DINUCLEAR ZN(II) COMPLEX; TRANSITION-STATE; RNA MODELS; CLEAVAGE; PHOSPHATE; CLUSTERS; SORPTION; HYDROLYSIS; EFFICIENT; POLYMER;

D O I：

10.1021/ic901504q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A polyoxometalate-based lanthanide-organic framework was achieved using the {[Ho-4(dpdo)(8)(H2O)(16)BW12O40] (H2O)(2)}(7+) nanocage as a secondary building block for the heterogeneous catalysis of phosphodiester cleavage in an aqueous solution.

引用

页码：1280 / 1282

页数：3

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