The exciting chemistry of tetraazidomethane

被引：126

作者：

Banert, Klaus ^{[1
]}

Joo, Young-Hyuk ^{[1
]}

Rueffer, Tobias ^{[1
]}

Walfort, Bernhard ^{[1
]}

Lang, Heinrich ^{[1
]}

机构：

[1] Tech Univ Chemnitz, D-09111 Chemnitz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 07期

关键词：

azides; dipolar cycloaddition; explosives; nitrogen heterocycles; nucleophilic substitution;

D O I：

10.1002/anie.200603960

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Chemical Equation Presented) With a nitrogen content of 93.3%, "perazidomethane(CN12) is highly explosive but nevertheless isolable. The title compound, which is accessible from commercially available trichloroacetonitrile in one step, undergoes simple dissociation and trapping reactions as well as more-complex transformations (for example, in the presence of norbornene; see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1168 / 1171

页数：4

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