Allyl/alkyne coupling reactions mediated by neutral ruthenium(II).: Isolation and characterization of ruthenium(II) η3-allyl η2-alkyne complexes

被引：14

作者：

Older, CM ^{[1
]}

Stryker, JM ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 14期

关键词：

D O I：

10.1021/om000275n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In contrast to the cyclization products obtained from allyl/alkyne coupling reactions in the isostructural cationic series, neutral complexes of the form (C5Me5)Ru(eta(3)-allyl)(eta(2)-alkyne) react to give acyclic eta(5)-pentadienyl complexes in high yield.

引用

页码：2661 / 2663

页数：3

共 55 条

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