Chemoselective deprotection of tertiary benzylamines and reduction of carbon-carbon double bonds in the presence of benzyl and benzyloxymethyl ethers

被引：23

作者：

Bajwa, JS ^{[1
]}

Slade, J ^{[1
]}

Repic, O ^{[1
]}

机构：

[1] Novarits Inst Biomed Res, E Hanover, NJ 07936 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 32期

关键词：

chemoselective; deprotection; benzylamines; reduction; olefins;

D O I：

10.1016/S0040-4039(00)01013-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic transfer hydrogenation using 10% Pd-C in the presence of 1,4-cyclohexadiene as the hydrogen donor selectively debenzylates amines and reduces carbon-carbon double bonds while leaving benzyl and benzyloxymethyl ethers intact. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：6025 / 6028

页数：4

共 19 条

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