Vanadium-catalyzed asymmetric oxidations

被引：313

作者：

Bolm, C ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

COORDINATION CHEMISTRY REVIEWS | 2003年 / 237卷 / 1-2期

关键词：

asymmetric catalysis; enantioselectivity; epoxides; sulfoxides; vanadium;

D O I：

10.1016/S0010-8545(02)00249-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chirally modified vanadium complexes have been used as catalysts in enantioselective epoxidations of allylic alcohols and asymmetric sulfide to sulfoxide oxidations. For both reactions various combinations of chiral ligands and vanadium sources have been tested. The results of previous work and those of current investigations are discussed and details of the catalysis with respect to enantioselectivity and catalyst turnover is presented. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：245 / 256

页数：12

共 183 条

[91] Design of optically active hydroxamic acids as ligands in vanadium-catalyzed asymmetric epoxidation
Hoshino, Y
Murase, N
Oishi, M
Yamamoto, H
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (07) : 1653 - 1658
[92] MULTIMACROCYCLIC COMPOUNDS .4. INTERNAL TRIMERISATION OF TRIPLE BONDS OF LINEAR TRIYNES ON A ZIEGLER CATALYST
HUBERT, AJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (20): : 1984 - &
[93] Towards a total synthesis of ustiloxins A & B. Stereocontrolled synthesis of (2S,4S,6S)-4-hydroxy-5-phenylsulfinylnorvaline
Hutton, CA
White, JM
[J]. TETRAHEDRON LETTERS, 1997, 38 (09) : 1643 - 1646
[94] Asymmetric catalysis of new generation chiral metallosalen complexes
Ito, YN
Katsuki, T
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (04) : 603 - 619
[95] JACOBSEN EN, 1993, CATALYTIC ASYMMETRIC, V1, P159
[96] KAGAN HB, 1998, ORGANOSULFUR CHEM, V2, P1
[97] Effect of portionwise addition of oxidant in asymmetric vanadium-catalyzed sulfide oxidation
Karpyshev, NN
Yakovleva, OD
Talsi, EP
Bryliakov, KP
Tolstikova, OV
Tolstikov, AG
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 157 (1-2) : 91 - 95
[98] Mn-salen catalyst, competitor of enzymes, for asymmetric epoxidation
Katsuki, T
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 113 (1-2) : 87 - 107
[99] CATALYTIC ASYMMETRIC OXIDATIONS USING OPTICALLY-ACTIVE (SALEN)MANGANESE(III) COMPLEXES AS CATALYSTS
KATSUKI, T
[J]. COORDINATION CHEMISTRY REVIEWS, 1995, 140 : 189 - 214
[100] THE 1ST PRACTICAL METHOD FOR ASYMMETRIC EPOXIDATION
KATSUKI, T
SHARPLESS, KB
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) : 5974 - 5976

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