Phosphorus-containing dendrimers and their transition metal complexes as efficient recoverable multicenter homogeneous catalysts in organic synthesis

被引：137

作者：

Maraval, V ^{[1
]}

Laurent, R ^{[1
]}

Caminade, AM ^{[1
]}

Majoral, JP ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 20期

关键词：

D O I：

10.1021/om0005607

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metalladendrimers of generation 3 with either 24 terminal palladium or ruthenium diphosphine complexes or one ruthenium diphosphine complex located at the core have been found to be efficient, recoverable catalysts in three general organic reactions: Stille couplings, Knoevenagel condensations, and Michael additions.

引用

收藏

页码：4025 / 4029

页数：5

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共 62 条

[31] Dendrimers containing heteroatoms (Si, P, B, Ge, or Bi) [J].

Majoral, JP ;

Caminade, AM .

CHEMICAL REVIEWS, 1999, 99 (03) :845-880

[32] Dendritic catalysts: Reactivity and mechanism of the dendritic bis(oxazoline)metal complex catalyzed Diels-Alder reaction [J].

Mak, CC ;

Chow, HF .

MACROMOLECULES, 1997, 30 (04) :1228-1230

[33] Rapid synthesis of phosphorus-containing dendrimers with controlled molecular architectures: First example of surface-block, layer-block, and segment-block dendrimers issued from the same dendron [J].

Maraval, V ;

Laurent, R ;

Donnadieu, B ;

Mauzac, M ;

Caminade, AM ;

Majoral, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (11) :2499-2511

[34] Towards golf ball shaped reagents: dendrimer fixed concave pyridines [J].

Marquardt, T ;

Luning, U .

CHEMICAL COMMUNICATIONS, 1997, (17) :1681-1682

[35] The use of a ten-membered tetraphosphole macrocycle to increase the lifetime of a palladium catalyst [J].

Mercier, F ;

Laporte, F ;

Ricard, L ;

Mathey, F ;

Schroder, M ;

Regitz, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (21) :2364-2366

[36] ELECTROCHEMICAL REDUCTION OF CO2 CATALYZED BY SMALL ORGANOPHOSPHINE DENDRIMERS CONTAINING PALLADIUM [J].

MIEDANER, A ;

CURTIS, CJ ;

BARKLEY, RM ;

DUBOIS, DL .

INORGANIC CHEMISTRY, 1994, 33 (24) :5482-5490

[37] Catalysis of dendrimer-bound Pd(II) complex - Selective hydrogenation of conjugated dienes to monoenes [J].

Mizugaki, T ;

Ooe, M ;

Ebitani, K ;

Kaneda, K .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 145 (1-2) :329-333

[38] Dendritic catalysts for the nitroaldol (Henry) reaction [J].

Morao, I ;

Cossio, FP .

TETRAHEDRON LETTERS, 1997, 38 (36) :6461-6464

[39] Ruthenium-catalyzed aldol and Michael reactions of nitriles. Carbon-carbon bond formation by alpha-C-H activation of nitriles [J].

Murahashi, SI ;

Naota, T ;

Taki, H ;

Mizuno, M ;

Takaya, H ;

Komiya, S ;

Mizuho, Y ;

Oyasato, N ;

Hiraoka, M ;

Hirano, M ;

Fukuoka, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (50) :12436-12451

[40] Computational investigations into the potential use of poly(benzyl phenyl ether) dendrimers as supports for organometallic catalysts [J].

Naidoo, KJ ;

Hughes, SJ ;

Moss, JR .

MACROMOLECULES, 1999, 32 (02) :331-341

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