A novel soluble poly(fluorenylenevinylene) conjugated polymer:: synthesis, characterization and application to optoelectronic devices

被引：30

作者：

Gruber, J

Li, RWC

Aguiar, LHJMC

Benvenho, ARV

Lessmann, R

Hümmelgen, IA

机构：

[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil

[2] Univ Fed Parana, Dept Fis, BR-81531990 Curitiba, Parana, Brazil

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 04期

关键词：

D O I：

10.1039/b411063c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the synthesis and characterization of poly(9,9-dioctyl-1,4-fluorenylenevinylene), PDO14FV. This polymer is a novel poly(arylenevinylene) with fluorene units and long chain substituents that ensure solubility in organic solvents. PDO14FV presents green photoluminescence and yellow-green electroluminescence. The estimated ionization potential of PDO14FV is 5.3 eV and its estimated electroaffinity 2.5 eV. Organic light-emitting diodes based on PDO14FV were constructed, showing electroluminescent intensity onset at ca. 6 V.

引用

收藏

页码：517 / 522

页数：6

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