Mass spectrometry in polymer chemistry: a state-of-the-art up-date

被引：188

作者：

Gruendling, Till ^{[2
,3
]}

Weidner, Steffen ^{[1
]}

Falkenhagen, Jana ^{[1
]}

Barner-Kowollik, Christopher ^{[2
]}

机构：

[1] BAM Fed Inst Mat Res & Testing, D-12489 Berlin, Germany

[2] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany

[3] Univ New S Wales, Bioanalyt Mass Spectrometry Facil, UNSW Analyt Ctr, Sydney, NSW 2052, Australia

来源：

POLYMER CHEMISTRY | 2010年 / 1卷 / 05期

关键词：

FREE-RADICAL POLYMERIZATION; SIZE-EXCLUSION CHROMATOGRAPHY; COLLISION-INDUCED DISSOCIATION; END-GROUP ANALYSIS; ATMOSPHERIC-PRESSURE PHOTOIONIZATION; THIOKETONE-MEDIATED POLYMERIZATION; MOLECULAR-WEIGHT DISTRIBUTIONS; SILVER-CATIONIZED POLYSTYRENES; DEGRADATION-PRODUCT PATTERNS; ELECTROSPRAY-IONIZATION;

D O I：

10.1039/b9py00347a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two decades after the introduction of matrix assisted laser desorption/ionization (MALDI) and electrospray ionization (ESI), soft ionization mass spectrometry represents a powerful toolset for the structural investigation of synthetic polymers. The present review highlights the current state-of-the-art, covering the latest developments of novel techniques, enabling instrumentation as well as the important applications of soft ionization MS from the beginning of 2008. Special attention is paid to the role that soft ionization MS has played in the mechanistic investigation of radical polymerization processes since 2005.

引用

页码：599 / 617

页数：19

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