Mass spectrometry in polymer chemistry: a state-of-the-art up-date

被引：188

作者：

Gruendling, Till ^{[2
,3
]}

Weidner, Steffen ^{[1
]}

Falkenhagen, Jana ^{[1
]}

Barner-Kowollik, Christopher ^{[2
]}

机构：

[1] BAM Fed Inst Mat Res & Testing, D-12489 Berlin, Germany

[2] KIT, Inst Tech Chem & Polymerchem, D-76128 Karlsruhe, Germany

[3] Univ New S Wales, Bioanalyt Mass Spectrometry Facil, UNSW Analyt Ctr, Sydney, NSW 2052, Australia

来源：

POLYMER CHEMISTRY | 2010年 / 1卷 / 05期

关键词：

FREE-RADICAL POLYMERIZATION; SIZE-EXCLUSION CHROMATOGRAPHY; COLLISION-INDUCED DISSOCIATION; END-GROUP ANALYSIS; ATMOSPHERIC-PRESSURE PHOTOIONIZATION; THIOKETONE-MEDIATED POLYMERIZATION; MOLECULAR-WEIGHT DISTRIBUTIONS; SILVER-CATIONIZED POLYSTYRENES; DEGRADATION-PRODUCT PATTERNS; ELECTROSPRAY-IONIZATION;

D O I：

10.1039/b9py00347a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two decades after the introduction of matrix assisted laser desorption/ionization (MALDI) and electrospray ionization (ESI), soft ionization mass spectrometry represents a powerful toolset for the structural investigation of synthetic polymers. The present review highlights the current state-of-the-art, covering the latest developments of novel techniques, enabling instrumentation as well as the important applications of soft ionization MS from the beginning of 2008. Special attention is paid to the role that soft ionization MS has played in the mechanistic investigation of radical polymerization processes since 2005.

引用

页码：599 / 617

页数：19

共 161 条

[81] Structural Analysis of Synthetic Polymer Mixtures Using Ion Mobility and Tandem Mass Spectrometry [J].

Hilton, Gillian R. ;

Jackson, Anthony T. ;

Thalassinos, Konstantinos ;

Scrivens, James H. .

ANALYTICAL CHEMISTRY, 2008, 80 (24) :9720-9725

[82] Fingerprinting the degradation product patterns of different polyester-ether networks by electrospray ionization mass Spectrometry [J].

Hoglund, Anders ;

Hakkarainen, Minna ;

Kowalczuk, Marek ;

Adamus, Grazyna ;

Albertsson, Ann-Christine .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (13) :4617-4629

[83] Solvent-free MALDI investigation of the cationization of linear polyethers with alkali metals [J].

Hortal, Ana R. ;

Hurtado, Paola ;

Martinez-Haya, Bruno ;

Arregui, Andres ;

Banares, Luis .

JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (29) :8530-8535

[84] Utilising matrix-assisted laser desorption/ionisation techniques for the generation of structural information from different end-group functionalised poly(methyl methacrylate)s [J].

Jackson, Anthony T. ;

Bunn, Alan ;

Chisholm, Michael S. .

POLYMER, 2008, 49 (24) :5254-5261

[85] Fast polymer fingerprinting using flowing afterglow atmospheric pressure glow discharge mass spectrometry [J].

Jecklin, Matthias C. ;

Gamez, Gerardo ;

Zenobi, Renato .

ANALYST, 2009, 134 (08) :1629-1636

[86] Quantitative Characterization of Solid Epoxy Resins Using Comprehensive Two Dimensional Liquid Chromatography Coupled with Electrospray Ionization-Time of Flight Mass Spectrometry [J].

Julka, Samir ;

Cortes, Hernan ;

Harfmann, Robert ;

Bell, Bruce ;

Schweizer-Theobaldt, Andreas ;

Pursch, Matthias ;

Mondello, Luigi ;

Maynard, Shawn ;

West, David .

ANALYTICAL CHEMISTRY, 2009, 81 (11) :4271-4279

[87] Self-directed formation of uniform unsaturated macromolecules from acrylate monomers at high temperatures [J].

Junkers, Tanja ;

Bennet, Francesca ;

Koo, Sandy P. S. ;

Barner-Kowollik, Christopher .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (10) :3433-3437

[88] The Role of Mid-Chain Radicals in Acrylate Free Radical Polymerization: Branching and Scission [J].

Junkers, Tanja ;

Barner-Kowollik, Christopher .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (23) :7585-7605

[89] Mapping poly(butyl acrylate) product distributions by mass Spectrometry in a wide temperature range: Suppression of midchain radical side reactions [J].

Junkers, Thomas ;

Koo, Sandy P. S. ;

Davis, Thomas P. ;

Stenzel, Martina H. ;

Barner-Kowollik, Christopher .

MACROMOLECULES, 2007, 40 (25) :8906-8912

[90] Thioketone-mediated polymerization of butyl acrylate: Controlling free-radical polymerization via a dormant radical species [J].

Junkers, Thomas ;

Stenzel, Martina H. ;

Davis, Thomas P. ;

Barner-Kowollik, Christopher .

MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (06) :746-753

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