Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

被引：654

作者：

Albrecht, Martin ^{[1
]}

机构：

[1] Natl Univ Ireland Univ Coll Dublin, Sch Chem & Chem Biol, Dublin 4, Ireland

来源：

CHEMICAL REVIEWS | 2010年 / 110卷 / 02期

基金：

欧洲研究理事会; 瑞士国家科学基金会;

关键词：

C-H ACTIVATION; N-HETEROCYCLIC-CARBENE; INTRAMOLECULAR-COORDINATION COMPOUNDS; RAY CRYSTAL-STRUCTURE; CARBON-HYDROGEN-BOND; ARYL RUTHENIUM(II) COMPLEXES; TERTIARY PHOSPHINE-LIGANDS; CYCLOMANGANATED (ETA(6)-ARENE)TRICARBONYLCHROMIUM COMPLEXES; ELECTROPHILIC AROMATIC-SUBSTITUTION; RESOLUTION OPTICAL SPECTROSCOPY;

D O I：

10.1021/cr900279a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted some of the fundamental aspects and the latest trends in the field of cyclometalation using d-block transition metals. It was revealed that cyclometalation had emerged as one of the most popular organometallic reactions, providing a simple entry to organometallic compounds. It allowed for the investigation of the essential aspects governing the metal-mediated activation of unreactive bonds, such as the C-H bond. The study covered seminal fundamental literature and the latest highlights and the trends that emerged till early 2009. Cyclometalation gained significance due to the reaction representing the mildest route for achieving strong C-H and C-R bonds. It had also emerged as an attractive and versatile synthetic method for creating organometallic entities with significantly wide application potential.

引用

页码：576 / 623

页数：48

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