MCM-41-supported bidentate phosphine palladium(0) complex as an efficient catalyst for the heterogeneous Suzuki reaction

被引：59

作者：

Cai, Mingzhong ^{[1
]}

Sha, Junchao ^{[1
]}

Xu, Qiuhua ^{[1
]}

机构：

[1] Jiangxi Normal Univ, Dept Chem, Nanchang 330027, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 268卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

supported palladium catalyst; bidentate phosphine palladium(0) complex; MCM-41; Suzuki reaction; heterogeneous catalysis;

D O I：

10.1016/j.molcata.2006.12.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

MCM-41-supported bidentate phosphine palladium(0) complex was conveniently synthesized from commercially available and cheap gamma-aminopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with diphenylphosphinomethanol and palladium chloride and then the reduction with hydrazine hydrate. The powder X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were employed to characterize the title palladium complex. It was found that this complex is a highly active catalyst for the heterogeneous Suzuki reaction of aryl halides with arylboronic acids and can be reused many times without loss of activity. (c) 2006 Elsevier B.V All rights reserved.

引用

页码：82 / 86

页数：5

共 33 条

[1] Solid-phase catalysis: A biomimetic approach toward ligands on dendritic arms to explore recyclable hydroformylation reactions [J].

Arya, P ;

Panda, G ;

Rao, NV ;

Alper, H ;

Bourque, SC ;

Manzer, LE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (12) :2889-2890

[2] An oxime-carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water [J].

Baleizao, C ;

Corma, A ;

García, H ;

Leyva, A .

CHEMICAL COMMUNICATIONS, 2003, (05) :606-607

[3] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[4] Preparation of a novel silica-supported palladium catalyst and its use in the Heck reaction [J].

Clark, JH ;

Macquarrie, DJ ;

Mubofu, EB .

GREEN CHEMISTRY, 2000, 2 (02) :53-55

[5]

Cornils B., 1996, APPL HOMOGENEOUS CAT, P576

[6] Supported catalysts and their applications in synthetic organic chemistry [J].

de Miguel, YR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2000, (24) :4213-4221

[7] TRANSFORMATIONS OF CHLOROARENES, CATALYZED BY TRANSITION-METAL COMPLEXES [J].

GRUSHIN, VV ;

ALPER, H .

CHEMICAL REVIEWS, 1994, 94 (04) :1047-1062

[8]

HUDKINS CMG, 2001, CHEM COMMUN, P2624

[9]

Kantam ML, 1999, SYNLETT, P1413

[10] Amphiphilic resin-supported ruthenium(II) complexes as recyclable catalysts for the hydrogenation of supercritical carbon dioxide [J].

Kayaki, Y ;

Shimokawatoko, Y ;

Ikariya, T .

ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (1-2) :175-179

← 1 2 3 4 →