An investigation of the factors that influence the decomposition of 7,7′,8,8′-tetracyanoquinodimethane (TCNQ) and its salts to, and structural characterization of, the α,α-dicyano-p-toluoylcyanide anion

被引：37

作者：

Grossel, MC ^{[1
]}

Duke, AJ

Hibbert, DB

Lewis, IK

Seddon, EA

Horton, PN

Weston, SC

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[2] SERC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

CHEMISTRY OF MATERIALS | 2000年 / 12卷 / 08期

关键词：

D O I：

10.1021/cm991160g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of formation of alpha,alpha-dicyano-p-toluoylcyanide anion (DCTC-) by reaction of TCNQ(0) and its radical anion salts with nitrite ion have been investigated spectroscopically; the reaction of TCNQ(0) with excess nitrite is first order, whereas oxidation of TCNQ(.-) appears to proceed via TCNQ(0) as an intermediate. The first X-ray structural study of a simple DCTC- salt, K+[2.2.2] DCTC-, is also reported.

引用

页码：2319 / 2323

页数：5

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