Synthesis of new sulfur-containing oxazoline ligands and their use in palladium-catalyzed allylic substitution

被引：31

作者：

Voituriez, A ^{[1
]}

Schulz, E ^{[1
]}

机构：

[1] Univ Paris 11, CNRS, UPRESA 8075, Inst Chim Mol Orsay,Lab Catalyse Mol, F-91405 Orsay, France

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 03期

关键词：

D O I：

10.1016/S0957-4166(02)00829-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New chiral sulfur-containing ligands have been prepared and fully characterized. Their structure includes a dibenzothiophene or benzothiophene ring as backbone, where the sulfur atom is enclosed in a strong pi-donor structure. The chirality was introduced by oxazoline moieties placed near the sulfur atom. These ligands have been successfully tested in asymmetric palladium-catalyzed allylic substitutions leading to products with ee of up to 77%. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：339 / 346

页数：8

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