Synthesis and characterization of 9-(cycloheptatrienylidene)fluorene derivatives: Acid-triggered "Switch on" of fluorophores

被引:27
作者
Wang, ZX [1 ]
Xing, YJ
Shao, HX
Lu, P
Weber, WP
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Univ So Calif, Loker Hydrocarbon Res Inst, Dept Chem, Los Angeles, CA 90089 USA
关键词
D O I
10.1021/ol047847a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of 9-(cycloheptatrienylidene)fluorene derivatives were synthesized in good yields through the Suzuki or Sonogashira cross-coupling reactions. Fluorescence "off-on" behaviors of these compounds were investigated on the basis of variable acid concentrations. These compounds were shown to be acid-sensing fluorophores with utility as indicators in acidic environments.
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收藏
页码:87 / 90
页数:4
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