μ-[7,8-bis(diphenylphosphino)-7,8-dicarba-nido-undecaborato-1κP,2κP′](pentafluoro-phenyl-1κC)(triphenylphosphine-2κP)-digold(I) dichloromethane solvate

被引：7

作者：

Crespo, O ^{[1
]}

Gimeno, MC ^{[1
]}

Laguna, A ^{[1
]}

Villacampa, MD ^{[1
]}

机构：

[1] Univ Zaragoza, Dept Quim Inorgan, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197013826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Au-2(C26H30B9P2)(C6F5)(C18H15P)].CH2Cl2, has a dinuclear structure with the diphosphinocarbaborane moiety bridging the two Au atoms. There is a short intramolecular Au Au contact of 2.9885 (8) Angstrom. The linear coordination at the Au-I atoms is highly distorted: P-Au-C 166.6(2) and P-Au-P 164.69(7)degrees. The open B3C2 face contains one bridging (B-H-B)H atom.

引用

页码：203 / 205

页数：3

共 22 条

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