A 3D Copper(II) Coordination Framework Showing Different Kinetic and Thermodynamic Crystal Transformations through Removal of Guest Water Cubes

被引：116

作者：

Chen, Xu-Dong ^{[1
]}

Zhao, Xiao-Hu ^{[1
]}

Chen, Min ^{[1
]}

Du, Miao ^{[1
]}

机构：

[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2009年 / 15卷 / 47期

基金：

中国国家自然科学基金;

关键词：

crystal engineering; kinetic control; metal-organic frameworks; supramolecular chemistry; thermodynamic control; SECONDARY BUILDING UNITS; SINGLE-CRYSTAL; STRUCTURAL TRANSFORMATIONS; MOLECULAR TECTONICS; NETWORK; DESIGN; POLYMERS; CHEMISTRY; DYNAMICS; CLUSTERS;

D O I：

10.1002/chem.200902306

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dual nature: A 3D CuII coordination framework 1·2H 2O shows distinct single-crystal to single-crystal transformations by removing guest cubic water clusters under different conditions, forming a pair of supramolecular isomers with a 3D lvt (threefold interpenetrating) or 2D kgm (Kagomé) network, which also reveals both rigid and flexible nature of this dual crystalline material (see scheme). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12974 / 12977

页数：4

共 49 条

[21] Crystalline-state guest-exchange and gas-adsorption phenomenon for a "Soft" supramolecular porous framework stacking by a rigid linear coordination polymer [J].