Polyaniline complex with fullerene C60

被引：101

作者：

Sapurina, I

Mokeev, M

Lavrentev, V

Zgonnik, V

Trchová, M

Hlavatá, D

Stejskal, J ^{[1
]}

机构：

[1] Acad Sci Czech Republ, Inst Macromol Chem, CR-16206 Prague 6, Czech Republic

[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia

[3] Charles Univ Prague, Fac Math & Phys, CR-18000 Prague 8, Czech Republic

来源：

EUROPEAN POLYMER JOURNAL | 2000年 / 36卷 / 11期

关键词：

polyaniline; fullerene; C-60; complex formation;

D O I：

10.1016/S0014-3057(00)00012-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyaniline-fullerene composites were prepared either by solid-state blending of both components (composite I) or by the introduction of fullerene during polymerization of aniline (composite II). Composite I had a lower conductivity (1.5 x 10(-7) S cm(-1)) than composite II (7.2 x 10(-5) S cm(-1)). Investigation of the composites by solid-state C-13-NMR and FTIR spectroscopy indicated the interaction between polyaniline and fullerene. X-ray diffractograms suggest that the mechanical blending of the components leads to a decrease in the size of fullerene crystallites. In composite II; the diffractograms proved the formation of a polyaniline-fullerene complex comprising the structure corresponding to a doped polyaniline. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：2321 / 2326

页数：6

共 41 条

[1] SUPERCONDUCTIVITY IN CONDUCTING POLYMER FULLERENCE COMPOSITE DOPED BY ALKALI-METAL [J].