学术探索
学术期刊
新闻热点
数据分析
智能评审

Impedance effect of an ion-sensitive membrane:: characterisation of an EMIS sensor by impedance spectroscopy, capacitance-voltage and constant-capacitance method

被引：49
作者：
Poghossian, A
Mai, DT
Mourzina, Y
Schöning, MJ
机构：
[1] Univ Appl Sci Aachen, Div Julich, Lab Chem Sensors & Biosensors, D-52428 Julich, Germany
[2] Res Ctr Julich, Inst Thin Films & Interfaces, ISG2, D-52425 Julich, Germany
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 2004年 / 103卷 / 1-2期
关键词：
silicon-based field-effect sensor; K+-sensitive EMIS structure; impedance spectroscopy; capacitance-voltage; constant-capacitance mode;
D O I：
10.1016/j.snb.2004.04.071
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The impedance effect of a thin polymer membrane on the characteristics of a capacitive electrolyte-membrane-insulator-semiconductor (EMIS) sensor has been investigated using a K+-sensitive EMIS sensor with a valinomycin-containing PVC membrane as a model system. The developed EMIS sensor has been studied by means of impedance spectroscopy, capacitance-voltage and constant-capacitance method. It is shown, that an improvement of the accuracy of the measurements can be achieved by means of correcting the capacitance-voltage curves using preliminary defined values of the membrane resistance and capacitance as well as by choosing an optimal working frequency range. The sensors' behaviour in terms of ion-sensitivity, stability, hysteresis, linear concentration range, detection limit and response time have been investigated, too. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：423 / 428
页数：6
相关论文
共 16 条
[1]   PROPERTIES OF PVC BASED MEMBRANES USED IN ION-SELECTIVE ELECTRODES [J].
ARMSTRONG, RD ;
HORVAI, G .
ELECTROCHIMICA ACTA, 1990, 35 (01) :1-7
[2]  
Bergveld P., 1988, Analytical and Biomedical Applications of Ion-Selective Field-Effect Transistors
[3]   MEMBRANES FOR CHEMICAL SENSORS [J].
CLECHET, P .
SENSORS AND ACTUATORS B-CHEMICAL, 1991, 4 (1-2) :53-63
[4]   On the analysis of C-V curves for high resistivity substrates [J].
delCueto, ME ;
Altuzarra, AC .
SOLID-STATE ELECTRONICS, 1996, 39 (10) :1519-1521
[5]   AN EQUIVALENT-CIRCUIT MODEL OF ION-SELECTIVE MEMBRANE BROKEN-VERTICAL-BAR INSULATOR BROKEN-VERTICAL-BAR SEMICONDUCTOR INTERFACES USED FOR CHEMICAL SENSORS [J].
DEMOZ, A ;
VERPOORTE, EMJ ;
HARRISON, DJ .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 389 (1-2) :71-78
[6]   The double K+/Ca2+ sensor based on laser scanned silicon transducer (LSST) for multi-component analysis [J].
Ermolenko, Y ;
Yoshinobu, T ;
Mourzina, Y ;
Furuichi, K ;
Levichev, S ;
Schöning, MJ ;
Vlasov, Y ;
Iwasaki, H .
TALANTA, 2003, 59 (04) :785-795
[7]   THE C-V METHOD FOR CHARACTERIZING ISFET OR EOS DEVICES WITH ION-SENSITIVE MEMBRANES [J].
FABRY, P ;
LAURENTYVONNOU, L .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 286 (1-2) :23-40
[8]  
GORDON BJ, 1993, SOLID STATE TECHNOL, V36, P57
[9]   Cytosensor® Microphysiometer:: technology and recent applications [J].
Hafner, F .
BIOSENSORS & BIOELECTRONICS, 2000, 15 (3-4) :149-158
[10]   CHARACTERIZATION OF ION-SENSITIVE LAYER SYSTEMS WITH A C(V) MEASUREMENT METHOD OPERATING AT CONSTANT CAPACITANCE [J].
KLEIN, M .
SENSORS AND ACTUATORS B-CHEMICAL, 1990, 1 (1-6) :354-356
12