Review: Synthetically modified carbohydrates as ligands

被引:34
作者
Alexeev, YE
Vasilchenko, IS
Kharisov, BI [1 ]
Blanco, LM
Garnovskii, AD
Zhdanov, YA
机构
[1] Univ Autonoma Nuevo, Fac Ciencias Quim, Monterrey, Mexico
[2] Rostov State Univ, Inst Phys & Organ Chem, Rostov Na Donu 344006, Russia
[3] Rostov State Univ, S Sci Ctr, Rostov Na Donu 344006, Russia
关键词
synthetic modification of carbohydrates; sugar-metal complexes; supramolecular structures; diastereoselective reactions;
D O I
10.1080/00958970412331297523
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The coordinative properties of synthetically modified carbohydrates to metal cations are reviewed. Such metal complexes are distinct, owing to the structural diversity of the ligands and coordination modes. The influences of complex-formation conditions on chemical properties of modified carbohydrates, as well as on organic reactions (especially diastereoselective ones), are examined. In addition, this manuscript demonstrates the practical importance of the coordination interactions.
引用
收藏
页码:1447 / 1517
页数:71
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