Structural and magnetic properties of a self-assembled spheroidal triakonta-hexanuclear Cu36 cluster

被引:53
作者
Abedin, TSM [1 ]
Thompson, LK [1 ]
Miller, DO [1 ]
Krupicka, E [1 ]
机构
[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada
关键词
D O I
10.1039/b211401c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An extended tritopic picolinic dihydrazide ligand with terminal oxime groups (dpocco) undergoes spontaneous self-assembly in the presence of copper acetate to produce a unique Cu-36 cluster exhibiting intramolecular anti-ferromagnetic exchange.
引用
收藏
页码:708 / 709
页数:2
相关论文
共 15 条
[1]   Multicomponent self-assembly: Preferential generation of a rectangular [2x3]G grid by mixed-ligand recognition [J].
Baxter, PNW ;
Lehn, JM ;
Kneisel, BO ;
Fenske, D .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (18) :1978-1981
[2]   1ST EXAMPLE OF A DISCRETE COPPER(III, II) MIXED-VALENCE COMPLEX - THE TRIANGULAR CUIIICUII2O CORE CIRCUMSCRIBED BY OXIME LIGANDS [J].
DATTA, D ;
CHAKRAVORTY, A .
INORGANIC CHEMISTRY, 1983, 22 (11) :1611-1613
[3]  
Garcia AM, 1999, CHEM-EUR J, V5, P1803, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1803::AID-CHEM1803>3.0.CO
[4]  
2-M
[5]   Towards nanostructured arrays of single molecule magnets: : new Fe19 oxyhydroxide clusters displaying high ground state spins and hysteresis [J].
Goodwin, JC ;
Sessoli, R ;
Gatteschi, D ;
Wernsdorfer, W ;
Powell, AK ;
Heath, SL .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (12) :1835-1840
[6]   Tetranuclear copper(II) and nickel(II) cluster complexes derived by self-assembly from a series of tetradentate diazine ligands: Structural and magnetic studies [J].
Matthews, CJ ;
Avery, K ;
Xu, ZQ ;
Thompson, LK ;
Zhao, L ;
Miller, DO ;
Biradha, K ;
Poirier, K ;
Zaworotko, MJ ;
Wilson, C ;
Goeta, AE ;
Howard, JAK .
INORGANIC CHEMISTRY, 1999, 38 (23) :5266-5276
[7]   Strategies for producing cluster-based magnetic arrays [J].
Schmitt, W ;
Murugesu, M ;
Goodwin, JC ;
Hill, JP ;
Mandel, A ;
Bhalla, R ;
Anson, CE ;
Heath, SL ;
Powell, AK .
POLYHEDRON, 2001, 20 (11-14) :1687-1697
[8]   Synthesis, structure, and magnetism of a series of self-assembled polynuclear Mn(II), Co(II), and Cu(II) cluster complexes [J].
Thompson, LK ;
Matthews, CJ ;
Zhao, L ;
Xu, ZQ ;
Miller, DO ;
Wilson, C ;
Leech, MA ;
Howard, JAK ;
Heath, SL ;
Whittaker, AG ;
Winpenny, REP .
JOURNAL OF SOLID STATE CHEMISTRY, 2001, 159 (02) :308-320
[9]   Structural and magnetic properties of dicopper(II) complexes of polydentate diazine ligands [J].
Thompson, LK ;
Xu, ZQ ;
Goeta, AE ;
Howard, JAK ;
Clase, HJ ;
Miller, DO .
INORGANIC CHEMISTRY, 1998, 37 (13) :3217-3229
[10]   Serendipitous assembly of polynuclear cage compounds [J].
Winpenny, REP .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (01) :1-10