Switching of molecular spin states in inorganic complexes by temperature, pressure, magnetic field and light:: Towards molecular devices

被引：200

作者：

Bousseksou, A

Molnár, G

Matouzenko, G

机构：

[1] Ecole Normale Super Lyon, Chim Lab, CNRS, UMR, F-69364 Lyon, France

[2] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 22期

关键词：

spin crossover; metastability; hysteresis loop; pressure; magnetic field; dielectric properties; ising-like model;

D O I：

10.1002/ejic.200400571

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The spin crossover phenomenon in molecular inorganic compounds is one of the most spectacular examples of bistability phenomena leading to a switching between the high-spin and the low-spin states of the molecule by several means such as temperature, pressure, light and magnetic field (multi-property molecular switching). In the present micro-review we report our most important findings, both experimental results and theoretical approaches, and discuss possible technological applications for each switching method as well as the recent synthesis of new spin crossover molecular materials.

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收藏

页码：4353 / 4369

页数：17

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