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Carbon-carbon bond forming reactions mediated by silicon Lewis acids

被引：215
作者：
Dilman, AD
Ioffe, SL
机构：
[1] Univ Paris 11, Inst Chim Mol Orsay, Lab Synth Asymetr, F-91405 Orsay, France
[2] ND Zelinskii Inst Organ Chem, Moscow 119991, Russia
来源：
CHEMICAL REVIEWS | 2003年 / 103卷 / 03期
关键词：
D O I：
10.1021/cr020003p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Data on the behavior of silicon Lewis acids (SLAs) of the general formula R3SiX in carbon-carbon bond forming processes are reviewed. The cycloaddition and conjugate addition reactions are also covered. The effects of interactions of Lewis acids with substrates on chemo-, regio, and stereoselectivity of reactions are discussed in detail.
引用
收藏
页码：733 / 772
页数：40
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