Iridium-catalyzed synthesis of primary allylic amines from allylic alcohols: Sulfamic acid as amonia equivalent

被引：352

作者：

Defieber, Christian ^{[1
]}

Ariger, Martin A. ^{[1
]}

Moriel, Patricia ^{[1
]}

Carreira, Erick M. ^{[1
]}

机构：

[1] ETH, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 17期

关键词：

D O I：

10.1002/anie.200700159

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Two for the price of one: Sulfamic acid serves not only as a nitrogen source but also as an in situ activator of hydroxy groups in the first direct iridium-catalyzed synthesis of primary allylic amines from allylic alcohols (see scheme; cod = cycloocta-1,5-diene). The reaction is catalyzed by a commercially available iridium complex and a phosphoramidite-based bidentate phosphorus-olefin ligand. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：3139 / 3143

页数：5

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