Nanoscale Homochiral C3-Symmetric Mixed-Valence Manganese Cluster Complexes with Both Ferromagnetic and Ferroelectric Properties

被引:180
作者
Liu, Cai-Ming [1 ]
Xiong, Ren-Gen [2 ]
Zhang, De-Qing [1 ]
Zhu, Dao-Ben [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China
基金
中国国家自然科学基金;
关键词
SINGLE-MOLECULE MAGNETS; HIGH-SPIN MOLECULES; CRYSTAL; TETRANUCLEAR; CHIRALITY; SYMMETRY;
D O I
10.1021/ja910310p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Both ferromagnetic and ferroelectric properties were observed in two enantiomerically pure nanoscale manganese cluster complexes supported by chiral Schiff base ligands, each of which comprises a 22-nucleus mixed-valence manganese(II/III) supratetrahedral cluster cation and an equilateral-triangle trinuclear manganese(III) cluster anion with C-3 symmetry.
引用
收藏
页码:4044 / +
页数:3
相关论文
共 40 条
[1]  
Afrati T, 2002, ANGEW CHEM INT EDIT, V41, P2148, DOI 10.1002/1521-3773(20020617)41:12<2148::AID-ANIE2148>3.0.CO
[2]  
2-R
[3]   High-spin molecules:: Hexanuclear MnIII clusters with [Mn6O4X4]6+ (X = Cl-, Br-) face-capped octahedral cores and S=12 ground states [J].
Aromí, G ;
Knapp, MJ ;
Claude, JP ;
Huffman, JC ;
Hendrickson, DN ;
Christou, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (23) :5489-5499
[4]   High-spin molecules:: Hexanuclear [Mn6O4Cl4(Me2dbm)6] (Me2dbmH = 4,4′-dimethyldibenzoylmethane) with a near tetrahedral [Mn6O4Cl4]6+ core and a S=12 ground state [J].
Aromí, G ;
Claude, JP ;
Knapp, MJ ;
Huffman, JC ;
Hendrickson, DN ;
Christou, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (12) :2977-2978
[5]   A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene [J].
Bi, Yanfeng ;
Wang, Xiu-Teng ;
Liao, Wuping ;
Wang, Xiaofei ;
Wang, Xinwu ;
Zhang, Hongjie ;
Gao, Song .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (33) :11650-+
[6]   Molecular spintronics using single-molecule magnets [J].
Bogani, Lapo ;
Wernsdorfer, Wolfgang .
NATURE MATERIALS, 2008, 7 (03) :179-186
[7]   Evidence of intermolecular π-stacking enhancement of second-harmonic generation in a family of single chain magnets [J].
Bogani, Lapo ;
Cavigli, Lucia ;
Bernot, Kevin ;
Sessoli, Roberta ;
Gurioli, Massimo ;
Gatteschi, Dante .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (26) :2587-2592
[8]   Single-molecule magnets [J].
Christou, George ;
Gatteschi, Dante ;
Hendrickson, David N. ;
Sessoli, Roberta .
MRS Bulletin, 2000, 25 (11) :66-71
[9]   Ferroelectric porous molecular crystal, [Mn3(HCOO)6](C2H5OH), exhibiting ferrimagnetic transition [J].
Cui, HengBo ;
Wang, Zheming ;
Takahashi, Kazuyuki ;
Okano, Yoshinori ;
Kobayashi, Hayao ;
Kobayashi, Akiko .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (47) :15074-15075
[10]   Enantiomerically pure polytungstates: Chirality transfer through zirconium coordination centers to nanosized inorganic clusters [J].
Fang, XK ;
Anderson, TM ;
Hill, CL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) :3540-3544