Synthesis and molecular structure of trans-IrCl(coe)(tBu2PH)2] (coe = cis-cyclooetene)

被引：11

作者：

Boettcher, Hans-Christian ^{[1
]}

Graf, Marion ^{[1
]}

Karaghiosoff, Konstantin ^{[1
]}

Mayer, Peter ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 5-6期

关键词：

iridium; olefinic complexes; phosphane ligands; crystal structure;

D O I：

10.1002/zaac.200700069

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [{lr(mu-Cl)(coe)(2)}(2)] (1) (Coe = cis-cyclo octene) with the secondary phosphane (Bu2PH)-Bu-1 afforded, under defined conditions, the novel complex tr(trans-[IrC](coe)((Bu2PH)-Bu-1)(2)] (2), which has been characterized by spectroscopic methods as well as by X-ray diffraction. Compound 2 represents the first isolated and structurally characterized type of complex trans-[IrCl(coe) L-2] (L = phosphane). The compound is presumably isolable because of the convenient electronic effects of the chosen phosphane ligands.

引用

页码：913 / 916

页数：4

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