Synthesis and use of bisoxazolinyl-phenyl pincers

被引：196

作者：

Nishiyama, Hisao ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 464, Japan

来源：

CHEMICAL SOCIETY REVIEWS | 2007年 / 36卷 / 07期

关键词：

D O I：

10.1039/b605991k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bisoxazolinyl-phenyl (Phebox) ligand is an example of an N, C, N tridentate (pincer type) ligand, which has a central carbon - metal covalent bond and two oxazolines. In this tutorial review, synthetic methods to prepare bisoxazolinyl-phenyl derivatives and their transition-metal complexes including rhodium, iridium, platinum, palladium, nickel and copper, are summarized. In addition, several applications to homogeneous and asymmetric catalysis with chiral bisoxazolinyl-phenyl metal complexes have been reviewed.

引用

页码：1133 / 1141

页数：9

共 43 条

[1]

Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO

[2]

2-6

[3] SYNTHESIS OF OPTICALLY-ACTIVE BIS(2-OXAZOLINES) - CRYSTAL-STRUCTURE OF A 1,2-BIS(2-OXAZOLINYL)BENZENE.ZNCL2 COMPLEX [J].

BOLM, C ;

WEICKHARDT, K ;

ZEHNDER, M ;

RANFF, T .

CHEMISCHE BERICHTE, 1991, 124 (05) :1173-1180

[4] Cyclopropanation with diazomethane and bis(oxazoline)palladium(II) complexes [J].

Denmark, SE ;

Stavenger, RA ;

Faucher, AM ;

Edwards, JP .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (10) :3375-3389

[5] Highly diastereo- and enantioselective copper-catalyzed domino reduction/aldol reaction of ketones with methyl acrylate [J].

Deschamp, J ;

Chuzel, O ;

Hannedouche, J ;

Riant, O .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (08) :1292-1297

[6] Pyridine-2,6-bis(oxazolines), helpful ligands for asymmetric catalysts [J].

Desimoni, G ;

Faita, G ;

Quadrelli, P .

CHEMICAL REVIEWS, 2003, 103 (08) :3119-3154

[7] C2-symmetric chiral bis(oxazoline) ligands in asymmetric catalysis [J].

Desimoni, Giovanni ;

Faita, Giuseppe ;

Jorgensen, Karl Anker .

CHEMICAL REVIEWS, 2006, 106 (09) :3561-3651

[8] Nitrogen-containing ligands for asymmetric homogeneous and heterogeneous catalysis [J].

Fache, F ;

Schulz, E ;

Tommasino, ML ;

Lemaire, M .

CHEMICAL REVIEWS, 2000, 100 (06) :2159-2231

[9] Synthesis and X-ray crystal structure analysis of the first nickel bisoxazoline pincer complex [J].

Fossey, JS ;

Richards, CJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (19) :3056-3059

[10]

Fuller NO, 2005, SYNLETT, P1459

← 1 2 3 4 5 →