Enantiospecific synthesis of Λ and Λ [Ru(bPY)2ppy]+ and [Ru(bPY)2quo]+ (bpy=2,2′-bipyridine, ppy = phenylpyridine-H+, quo=8-hydroxyquinolate):: 1H and 13C NMR studies and X-ray structure determination of rac-[Ru(bpy)2quo]PF6

被引：38

作者：

Brissard, M

Convert, O

Gruselle, M

Guyard-Duhayon, C

Thouvenot, R

机构：

[1] Univ Paris 06, CNRS, UMR 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

[2] Univ Paris 06, CNRS, UMR 7613, Lab Chim Struct Organ & Biol, F-75252 Paris, France

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 04期

关键词：

D O I：

10.1021/ic026121c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this paper, we describe the enantiospecific synthesis and the complete characterization of the two hexacoordinated ruthenium(II) monocations [Ru(bpy)(2)ppy](+) and [Ru(bpy)(2)quo](+) (bpy = 2,2'-bipyridine, ppy = phenylpyridine-H+, quo = 8-hydroxyquinolate) in their enantiomeric Delta and Delta forms. The corresponding enantiomeric excesses (ee's) are determined by H-1 NMR using pure Delta-Trisphat (tris(tetrachlorobenzenedialato)phosphate(V) anion) as a chiral H-1 NMR shift reagent. A complete H-1 and C-13 NMR study has been carried out on rac-[Ru(bPY)(2)ppy]PF6 and rac-[Ru(bpy)(2)quo]PF6. Additionally, the X-ray molecular structure of rac-[Ru(bpy)(2)quo]PF6 is reported; this latter species crystallizes in the monoclinic C2/c space group (a = 22.079 Angstrom, b = 16.874 Angstrom, c = 17.533 Angstrom, (alpha = 90degrees, beta = 109.08degrees, gamma = 90degrees).

引用

收藏

页码：1378 / 1385

页数：8

相关论文

共 35 条

[21] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE [J].

JURIS, A ;

BALZANI, V ;

BARIGELLETTI, F ;

CAMPAGNA, S ;

BELSER, P ;

VONZELEWSKY, A .

COORDINATION CHEMISTRY REVIEWS, 1988, 84 :85-277

[22] PHOTOPHYSICS, PHOTOCHEMISTRY AND SOLAR-ENERGY CONVERSION WITH TRIS(BIPYRIDYL)RUTHENIUM(II) AND ITS ANALOGS [J].

KALYANASUNDARAM, K .

COORDINATION CHEMISTRY REVIEWS, 1982, 46 (OCT) :159-244

[23] Synthesis and resolution of the configurationally stable tris(tetrachlorobenzenediolato)phosphate(V) ion [J].

Lacour, J ;

Ginglinger, C ;

Grivet, C ;

Bernardinelli, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (06) :608-610

[24] (Ferrocenylmethyl)trialkyl ammoniums as template cations in optically active two-dimensional oxalate bridged [Cr-Mn] and [Cr-Ni] molecule-based magnets:: synthesis and magnetic properties [J].

Malézieux, B ;

Andrés, R ;

Brissard, M ;

Gruselle, M ;

Train, C ;

Herson, P ;

Troitskaya, LL ;

Sokolov, VI ;

Ovseenko, ST ;

Demeschik, TV ;

Ovanesyan, NS ;

Mamed'yarova, IA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 :182-190

[25] APPLICATION OF PHASE SENSITIVE TWO-DIMENSIONAL CORRELATED SPECTROSCOPY (COSY) FOR MEASUREMENTS OF H-1-H-1 SPIN-SPIN COUPLING-CONSTANTS IN PROTEINS [J].

MARION, D ;

WUTHRICH, K .

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1983, 113 (03) :967-974

[26] Highly diastereoselective preparation of ruthenium bis(diimine) sulfoxide complexes:: New concept in the preparation of optically active octahedral ruthenium complexes [J].

Pezet, F ;

Daran, JC ;

Sasaki, I ;

Aït-Haddou, H ;

Balavoine, GGA .

ORGANOMETALLICS, 2000, 19 (20) :4008-4015

[27] TRISPHAT anion. An efficient NMR chiral shift counterion for cationic tricarbonyl manganese complexes with planar chirality [J].

Planas, JG ;

Prim, D ;

Rose, E ;

Rose-Munch, F ;

Monchaud, D ;

Lacour, J .

ORGANOMETALLICS, 2001, 20 (19) :4107-4110

[28] [n-Bu4N][Δ-TRISPHAT] salt, an efficient NMR chiral shift reagent for neutral planar chiral tricarbonylchromium complexes [J].

Ratni, H ;

Jodry, JJ ;

Lacour, J ;

Kündig, EP .

ORGANOMETALLICS, 2000, 19 (19) :3997-3999

[29] THEORY OF OPTICAL-ACTIVITY IN THE LIGAND-FIELD TRANSITIONS OF CHIRAL TRANSITION-METAL COMPLEXES [J].

RICHARDSON, FS .

CHEMICAL REVIEWS, 1979, 79 (01) :17-36

[30] CHIRAL [RU(PP)(2)(CO)(2)](2+) SPECIES (PP=BIDENTATE POLYPYRIDYL LIGAND) AND THEIR USE IN THE STEREOSELECTIVE SYNTHESIS OF LIGAND-BRIDGED DINUCLEAR COMPLEXES [J].

RUTHERFORD, TJ ;

QUAGLIOTTO, MG ;

KEENE, FR .

INORGANIC CHEMISTRY, 1995, 34 (15) :3857-3858

← 1 2 3 4 →