Isoxazole→benzisoxazole rearrangement promoted cascade reactions affording stereodefined polycycles

被引：18

作者：

Bode, JW

Uesuka, H

Suzuki, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[2] Japan Sci & Technol Corp, CREST, Meguro Ku, Tokyo 1528551, Japan

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 04期

关键词：

D O I：

10.1021/ol0272848

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A new chemo-, regio-, and stereoselective cascade reaction features a novel isoxazole --> benzisoxazole rearrangement and affords highly functionalized, differentially protected compounds. The products of this reaction are directly converted to a number of complex, structurally diverse polycyclic molecules. These transformations highlight the unique chemistry inherent to readily prepared fused isoxazoles.

引用

页码：395 / 398

页数：4

共 19 条

[1]

[Anonymous], 1979, ADV HETEROCYCL CHEM

[2] A REGIOSELECTIVE SYNTHESIS OF 3-ISOPRENYL-4-HYDROXYCOUMARINS [J].