Mechanistic insight into organic and catalytic reactions by joint studies using mass spectrometry and NMR spectroscopy

被引:160
作者
Belyakov, Pavel A. [1 ]
Kadentsev, Valentine I. [1 ]
Chizhov, Alexander O. [1 ]
Kolotyrkina, Natal'ya G. [1 ]
Shashkov, Alexander S. [1 ]
Ananikov, Valentine P. [1 ]
机构
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Dept Struct Studies, IOC, Moscow 119991, Russia
关键词
C-13; CHEMICAL-SHIFTS; MAGNETIC-RESONANCE; PALLADIUM(II) COMPLEXES; ABSOLUTE-CONFIGURATION; STRUCTURAL ELUCIDATION; QUANTUM-CHEMISTRY; ESI-MS; IONIZATION; REACTIVITY; TOOL;
D O I
10.1016/j.mencom.2010.05.001
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Utilization of NMR spectroscopy and mass spectrometry for joint mechanistic and structural studies is a well-known practice. Several opportunities have appeared in recent years because of new hardware development and design of novel experimental procedures. Recent progress in this area and leading examples of new development, as well as already distinguished techniques, are discussed.
引用
收藏
页码:125 / 131
页数:7
相关论文
共 112 条
[1]
Monitoring of fluid motion in a micromixer by dynamic NMR microscopy [J].
Ahola, S ;
Casanova, F ;
Perlo, J ;
Münnemann, K ;
Blümich, B ;
Stapf, S .
LAB ON A CHIP, 2006, 6 (01) :90-95
[2]
Albert K., 2002, On-Line LC-NMR and Related Techniques
[3]
Computational chemistry:: A useful (sometimes mandatory) tool in mass spectrometry studies [J].
Alcamí, M ;
Mó, O ;
Yáñez, M .
MASS SPECTROMETRY REVIEWS, 2001, 20 (04) :195-245
[4]
Bronsted Acid Catalyzed Morita-Baylis-Hillman Reaction: A New Mechanistic View for Thioureas Revealed by ESI-MS(/MS) Monitoring and DFT Calculations [J].
Amarante, Giovanni W. ;
Benassi, Mario ;
Milagre, Humberto M. S. ;
Braga, Ataualpa A. C. ;
Maseras, Feliu ;
Eberlin, Marcos N. ;
Coelho, Fernando .
CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (45) :12460-12469
[5]
Amekraz B, 1996, NEW J CHEM, V20, P1011
[6]
Synthesis and structure of [Pt(CH=CI-CH2OCH3)2(I)2] as possible intermediate of catalytic alkynes conversion reaction into diiodosubstituted dienes [J].
Ananikov, V ;
Mitchenko, SA ;
Beletskaya, IP ;
Nefedov, SE ;
Eremenko, IL .
INORGANIC CHEMISTRY COMMUNICATIONS, 1998, 1 (11) :411-414
[7]
Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes [J].
Ananikov, V. P. ;
Beletskaya, I. P. .
RUSSIAN CHEMICAL BULLETIN, 2008, 57 (04) :754-760
[8]
Critical effect of phosphane ligands on the mechanism of carbon-carbon bond formation involving palladium(II) complexes: A theoretical investigation of reductive elimination from square-planar and T-shaped species [J].
Ananikov, Valentine P. ;
Musaev, Djamaladdin G. ;
Morokuma, Keiji .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 34 (34) :5390-5399
[9]
Nickel(II) chloride-catalyzed regioselective hydrothiolation of alkynes [J].
Ananikov, VP ;
Malyshev, DA ;
Beletskaya, IP ;
Aleksandrov, GG ;
Eremenko, IL .
ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (15) :1993-2001
[10]
Stereo- and regioselective functionalization of alkynes catalyzed by platinum(IV) and palladium(II) complexes in the system I--I3--H2O/MeOH [J].
Ananikov, VP ;
Mitchenko, SA ;
Beletskaya, IP .
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 38 (05) :636-650